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The paper uses inverted glancing angle deposition (I-GLAD) for creating antibacterial surfaces. Antibacterial surfaces are found in nature, such as on insect wings, eyes, and plant leaves. Since the bactericidal mechanism is purely physical for these surfaces, the antimicrobial resistance of bacteria to traditional chemical antibiotics can be overcome. The technical problem is how to mimic, synthesize, and scale up the naturally occurring antibacterial surfaces for practical applications, given the fact that most of those surfaces are composed of three-dimensional hierarchical micro-nano structures. This paper proposes to use I-GLAD as a novel bottom-up nanofabrication technique to scale up bio-inspired nano-structured antibacterial surfaces. Our innovative I-GLAD nanofabrication technique includes traditional GLAD deposition processes alongside the crucial inverting process. Following fabrication, we explore the antibacterial efficacy of I-GLAD surfaces using two types of bacteria:Escherichia coli(E. coli), a gram-negative bacterium, andStaphylococcus aureus(S. aureus), a gram-positive bacterium. Scanning electron microscopy (SEM) shows the small tips and flexibleD/P(feature size over period) ratio of I-GLAD nanoneedles, which is required to achieve the desired bactericidal mechanism. Antibacterial properties of the I-GLAD samples are validated by achieving flat growth curves ofE. coliandS. aureus, and direct observation under SEM. The paper bridges the knowledge gaps of seeding techniques for GLAD, and the control/optimization of the I-GLAD process to tune the morphologies of the nano-protrusions. I-GLAD surfaces are effective against both gram-negative and gram-positive bacteria, and they have tremendous potentials in hospital settings and daily surfaces.

 

Abstract This paper describes the fabrication of cicada-wing-inspired antimicrobial surfaces using Glancing Angle Deposition (GLAD). From the study of an annual cicada ( Neotibicen Canicularis , also known as dog-day cicada) in North America, it is found that the cicada wing surfaces are composed of unique three-dimensional (3D) nanofeature arrays, which grant them extraordinary properties including antimicrobial (antifouling) and antireflective. However, the morphology of these 3D nanostructures imposes challenges in artificially synthesizing the structures by utilizing and scaling up the template area from nature. From the perspective of circumventing the difficulties of creating 3D nanofeature arrays with top-down nanofabrication techniques, this paper introduces a nanofabrication process that combines bottom-up steps: self-assembled nanospheres are used as the bases of the features, while sub-100 nm pillars are grown on top of the bases by GLAD. Scanning electron micrographs show the resemblance of the synthesized cicada wing mimicry samples to the actual cicada wings, both quantitatively and qualitatively. The synthetic mimicry samples are hydrophobic with a water contact angle of 125˚. Finally, the antimicrobial properties of the mimicries are validated by showing flat growth curves of Escherichia coli ( E. coli ) and by direct observation under scanning electron microscopy (SEM). The process is potentially suitable for large-area antimicrobial applications in food and biomedical industries. 

A direct-write configuration of microsphere photolithography (MPL) is investigated for the patterning of IR metasurfaces at large scales. MPL uses a self-assembled hexagonal close-packed array of microspheres as an optical element to generate photonic nanojets within a photoresist layer. The photonic jets can be positioned within the microsphere-defined unit cells by controlling the illumination’s angle of incidence (AOI). This allows the definition of complex antenna elements. A digital micromirror device is used to provide spatial modulation across the microsphere arrays and coordinated with a set of stages providing AOI control. This provides hierarchical patterning at the sub- and super-unit cell levels and is suitable for a range of metasurfaces. The constraints of this approach are analyzed and demonstrated with a polarization-dependent infrared perfect absorber/emitter, which agrees well with modeling.

 

Aerosol Jet Printing shows a lot of promise for the future of printable electronics. It is compatible with a wide range of materials and can be printed on nearly any type of surface features because of its 3–5 mm standoff distance from the substrate. However, nearly all materials printed require some form of post-sintering processing to reduce the electrical resistance. Many companies develop these materials, but only provide a narrow range of post processing results to demonstrate the achievable conductivity values. In this paper, a design of experiment (DOE) is presented that demonstrates a way to characterize any material for Aerosol Jet Printing during and after post sintering processing by measuring conductivity with different time and temperature values. From these results, a linear regression model can be made to develop an equation that predicts conductivity at a given time-temperature value. This paper applies this method to Clariant Ag ink and sinters silver pads in an oven. A linear regression model is successfully developed that fits the data very well. From this model, an equation is derived to predict the conductivity of the Clariant Ag ink for any time-temperature value. Although only demonstrated with an oven and one type of ink, this method of experimentation and model development can be done with any material and any post processing method. 

Microsphere photolithography (MPL) is a fabrication technique that combines the ability to self-assemble arrays of microspheres with the ability of a microsphere to focus light to a photonic jet, in order to create highly ordered nanoscale features in photoresist. This paper presents a model of photoresist exposure with the photonic jet, combining a full-wave electromagnetic model of the microsphere/photoresist interaction with the sequential removal of exposed photoresist by the developer. The model is used to predict the dose curves for the MPL process based on the photoresist thickness, illumination conditions, and development time. After experimental validation, the model provides insight into the process including the resolution, sensitivity, and effects of off-normal illumination. This guides the fabrication of sub-100 nm hole/disk arrays using lift-off, and superposition is shown to predict the geometry for split-ring resonators created using multiple exposures. This model will assist synthesizing fabrication parameters to create large area scalable metasurfaces with sensing and energy management applications.

 

Atmospheric condensation is very important for multiple practical applications such as heat transfer, thermal management, aerospace, and condensate harvesting. Water droplets heterogeneously nucleate on the surfaces when the temperature is below the dew point temperature. The nucleation energy barrier for a condensed droplet varies significantly with the humidity content in the operating environment. The freezing of this condensate is also dependent on the operating conditions and surface properties. This article presents an experimental study of condensation and freezing from humid air with the objective of understanding how the surface morphology and chemistry determines the droplet shape and wetting state. Hexagonal close-packed arrays of titanium (Ti) pillars are patterned using microsphere photolithography (MPL). The Ti nanostructured surface was tested with and without a Teflon© coating to reveal the condensate harvesting, passive freezing, and dropwise condensation applications, respectively. Condensation and freezing tests were conducted in the presence of non-condensable gases (air) with different relative humidity (RH) levels to control the nucleation site density. The experiments showed that droplet growth occurs in the following stages: initial nucleation, direct growth, and coalescence events. By pinning droplets, coalescence is suppressed for the Ti nanopillared surface altering the size distribution of droplets and significantly accelerating the freezing process. 

Unconventional shale or tight oil/gas reservoirs that have micro-/nano-sized dual-scale matrix pore throats with micro-fractures may result in different fluid flow mechanisms compared with conventional oil/gas reservoirs. Microfluidic models, as a potential powerful tool, have been used for decades for investigating fluid flow at the pore-scale in the energy field. However, almost all microfluidic models were fabricated by using etching methods and very few had dual-scale micro-/nanofluidic channels. Herein, we developed a lab-based, quick-processing and cost-effective fabrication method using a lift-off process combined with the anodic bonding method, which avoids the use of any etching methods. A dual-porosity matrix/micro-fracture pattern, which can mimic the topology of shale with random irregular grain shapes, was designed with the Voronoi algorithm. The pore channel width range is 3 μm to 10 μm for matrices and 100–200 μm for micro-fractures. Silicon is used as the material evaporated and deposited onto a glass wafer and then bonded with another glass wafer. The channel depth is the same (250 nm) as the deposited silicon thickness. By using an advanced confocal laser scanning microscopy (CLSM) system, we directly visualized the pore level flow within micro/nano dual-scale channels with fluorescent-dyed water and oil phases. We found a serious fingering phenomenon when water displaced oil in the conduits even if water has higher viscosity and the residual oil was distributed as different forms in the matrices, micro-fractures and conduits. We demonstrated that different matrix/micro-fracture/macro-fracture geometries would cause different flow patterns that affect the oil recovery consequently. Taking advantage of such a micro/nano dual-scale ‘shale-like’ microfluidic model fabricated by a much simpler and lower-cost method, studies on complex fluid flow behavior within shale or other tight heterogeneous porous media would be significantly beneficial.